An Ireland-Claisen Approach to beta-Alkoxy alpha-Amino Acids
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A diastereoselective Ireland-Claisen approach to beta-alkoxy alpha-amino acid esters is reported. Amino acid esters of enol ethereal allylic alcohols undergo facile syn-selective [3,3]-sigmatropic rearrangement via silyl ketene acetals. Substrate synthesis, rearrangement development, stereoselectivity, and product elaboration are discussed.
|Creators||Tellam, J. P., Kociok-Kohn, G. and Carbery, D. R.|
|Departments||Faculty of Science > Chemistry|
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