Research

A Dinuclear Adduct of bis (di-sec-butyl dithiophosphato) Cadmium(II) Built around the Hexamethylenetetramine Cage as Coordination Center


Reference:

Bolundut, L., Haiduc, I., Mahon, M. F. and Molloy, K. C., 2008. A Dinuclear Adduct of bis (di-sec-butyl dithiophosphato) Cadmium(II) Built around the Hexamethylenetetramine Cage as Coordination Center. Revista De Chimie, 59 (11), pp. 1194-1196.

Related documents:

This repository does not currently have the full-text of this item.
You may be able to access a copy if URLs are provided below. (Contact Author)

Abstract

Bis(di-sec-butyldithiophosphato)cadmium(II) forms a 2:1 adduct with hexamethylenetetramine (urotropine), which was characterized by FT-IR and NMR spectroscopy. The compound is a dinuclear complex with the cadmium atoms coordinated at two nitrogen atoms of hexamethylenetetramine cage which is the actual coordination center. The X-ray diffraction analysis of the complex reveals a distorted square pyramidal coordination of the five-coordinate cadmium atoms. At each cadmium, one dithiophosphato, group behaves as slightly anisobidentate whereas the other one is an isobidentate chelating ligand.

Details

Item Type Articles
CreatorsBolundut, L., Haiduc, I., Mahon, M. F. and Molloy, K. C.
Uncontrolled Keywordscoordination center, dinuclear complex, crystal structure, hexamethylenetetramine
DepartmentsFaculty of Science > Chemistry
RefereedYes
StatusPublished
ID Code12419

Export

Actions (login required)

View Item