A Dinuclear Adduct of bis (di-sec-butyl dithiophosphato) Cadmium(II) Built around the Hexamethylenetetramine Cage as Coordination Center

Reference:

Bolundut, L., Haiduc, I., Mahon, M. F. and Molloy, K. C., 2008. A Dinuclear Adduct of bis (di-sec-butyl dithiophosphato) Cadmium(II) Built around the Hexamethylenetetramine Cage as Coordination Center. Revista De Chimie, 59 (11), pp. 1194-1196.

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Abstract

Bis(di-sec-butyldithiophosphato)cadmium(II) forms a 2:1 adduct with hexamethylenetetramine (urotropine), which was characterized by FT-IR and NMR spectroscopy. The compound is a dinuclear complex with the cadmium atoms coordinated at two nitrogen atoms of hexamethylenetetramine cage which is the actual coordination center. The X-ray diffraction analysis of the complex reveals a distorted square pyramidal coordination of the five-coordinate cadmium atoms. At each cadmium, one dithiophosphato, group behaves as slightly anisobidentate whereas the other one is an isobidentate chelating ligand.

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