Gilman-Type versus Lipshutz-Type Reagents: Competition in Lithiocuprate Chemistry
Reference:
Haywood, J., Morey, J. V., Wheatley, A. E. H., Liu, C. Y., Yasuike, S., Kurita, J., Uchiyama, M. and Raithby, P. R., 2009. Gilman-Type versus Lipshutz-Type Reagents: Competition in Lithiocuprate Chemistry. Organometallics, 28 (1), pp. 38-41.
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Official URL:
http://dx.doi.org/10.1021/om801101u
Abstract
CuCN reacts with RLi and TMPLi (TMP = 2,2.6,6-tetramethylpiperidide) to give Gilman-type cuprates R(TMP)CuLi.nL (R = Ph, n = 3, L = THF 2; R = Me, n = 1, L = TMEDA 3). 3 and 3.LiCN have been tested in directed ortho cupration with data suggesting enhanced efficiency for Lipshutz-type 3.LiCN; competition between Lipshutz- and Gilman-type formulations is rationalized by DFT methods.
Details
| Item Type | Articles |
| Creators | Haywood, J., Morey, J. V., Wheatley, A. E. H., Liu, C. Y., Yasuike, S., Kurita, J., Uchiyama, M. and Raithby, P. R. |
| DOI | 10.1021/om801101u |
| Departments | Faculty of Science > Chemistry |
| Refereed | Yes |
| Status | Published |
| ID Code | 12517 |
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