Transition metal catalysed reactions of alcohols using borrowing hydrogen methodology
Reference:
Nixon, T. D., Whittlesey, M. K. and Williams, J. M. J., 2009. Transition metal catalysed reactions of alcohols using borrowing hydrogen methodology. Dalton Transactions, 5, pp. 753-762.
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Official URL:
http://dx.doi.org/10.1039/b813383b
Abstract
The reactivity of alcohols can be enhanced by the temporary removal of hydrogen using a transition metal catalyst to generate an intermediate aldehyde or ketone. The so-formed carbonyl compound has a greater reactivity towards nucleophilic addition accommodating the in situ formation of imines or alkenes. The return of hydrogen from the catalyst leads to the formation of new C-N and C-C bonds, often with water as the only reaction by-product.
Details
| Item Type | Articles |
| Creators | Nixon, T. D., Whittlesey, M. K. and Williams, J. M. J. |
| DOI | 10.1039/b813383b |
| Uncontrolled Keywords | ketones, carbonylation, metal recovery, hydrocarbons, transition metals, olefins, organic compounds, hydrogen, nitrogen compounds, aldehydes, hydrogen bonds, catalysis |
| Departments | Faculty of Science > Chemistry |
| Refereed | Yes |
| Status | Published |
| ID Code | 12704 |
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