Stereoselective double Friedel-Crafts alkylation of indoles with divinyl ketones
Silvanus, A. C., Heffernan, S. J., Liptrot, D. J., Kociok-Kohn, G., Andrews, B. I. and Carbery, D. R., 2009. Stereoselective double Friedel-Crafts alkylation of indoles with divinyl ketones. Organic Letters, 11 (5), pp. 1175-1178.
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A tandem double Friedel-Crafts reaction of indoles and nonsymmetrical divinyl ketones has been achieved. The tandem reaction forms complex [6-5-7]-tricyclic Indoles in excellent yields. The reaction is completely regioselective and offers high levels of syn diastereoselectivity. The reaction Is also seen to be sensitive to substrate structure and catalyst.
|Creators||Silvanus, A. C., Heffernan, S. J., Liptrot, D. J., Kociok-Kohn, G., Andrews, B. I. and Carbery, D. R.|
|Departments||Faculty of Science > Chemistry|
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