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Amine-triggered molecular capsules using dynamic boronate esterification


Reference:

Kataoka, K., Okuyama, S., Minami, T., James, T. D. and Kubo, Y., 2009. Amine-triggered molecular capsules using dynamic boronate esterification. Chemical Communications, 13, pp. 1682-1684.

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Official URL:

http://dx.doi.org/10.1039/b900102f

Abstract

Boron-contained molecular capsules triggered by amines are described for the first time; when Et3N was employed as a chemical stimulus the Lewis acid Et3NH+, produced by solvolysis reaction on the boron, was found to be encapsulated in the internal cavity, whereas use of (Bu3N)-Bu-n led to the related dynamic capsule capable of accommodating several guest species including Cs+.

Details

Item Type Articles
CreatorsKataoka, K., Okuyama, S., Minami, T., James, T. D. and Kubo, Y.
DOI10.1039/b900102f
DepartmentsFaculty of Science > Chemistry
RefereedYes
StatusPublished
ID Code13892

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