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Polymerisation resistant synthesis of methacrylamido phenylboronic acids


Reference:

D'Hooge, F., Rogalle, D., Thatcher, M. J., Perera, S., van den Elsen, J. M. H., Jenkins, T. A., James, T. and Fossey, J., 2008. Polymerisation resistant synthesis of methacrylamido phenylboronic acids. Polymer, 49 (16), pp. 3362-3365.

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Official URL:

http://dx.doi.org/10.1016/j.polymer.2008.05.039

Abstract

Acrylamido boronic acids are important building blocks for functional polymers but suffer from poor synthetic strategies and unwanted polymerisation. A two-step deprotection of pinacolato methacrylamido phenylene boronic esters to generate 2-, 3- and 4-methacrylamido phenylboronic acids in good yield and purity is reported. Boronic acid containing methacrylamido monomers are now available in good yields for incorporation into polymers.

Details

Item Type Articles
CreatorsD'Hooge, F., Rogalle, D., Thatcher, M. J., Perera, S., van den Elsen, J. M. H., Jenkins, T. A., James, T. and Fossey, J.
DOI10.1016/j.polymer.2008.05.039
Uncontrolled Keywordsacrylamide, boronic acid, deprotection
DepartmentsFaculty of Engineering & Design > Chemical Engineering
Faculty of Science > Biology & Biochemistry
Faculty of Science > Chemistry
RefereedYes
StatusPublished
ID Code14765

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