Polymerisation resistant synthesis of methacrylamido phenylboronic acids

Reference:

D'Hooge, F., Rogalle, D., Thatcher, M. J., Perera, S., van den Elsen, J. M. H., Jenkins, T. A., James, T. and Fossey, J., 2008. Polymerisation resistant synthesis of methacrylamido phenylboronic acids. Polymer, 49 (16), pp. 3362-3365.

Related documents:

Official URL:

http://dx.doi.org/10.1016/j.polymer.2008.05.039

Abstract

Acrylamido boronic acids are important building blocks for functional polymers but suffer from poor synthetic strategies and unwanted polymerisation. A two-step deprotection of pinacolato methacrylamido phenylene boronic esters to generate 2-, 3- and 4-methacrylamido phenylboronic acids in good yield and purity is reported. Boronic acid containing methacrylamido monomers are now available in good yields for incorporation into polymers.

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