Synthesis of furans, pyrroles and pyridazines by a ruthenium-catalysed isomerisation of alkynediols and in situ cyclisation
Pridmore, S. J., Slatford, P. A., Taylor, J. E., Whittlesey, M. K. and Williams, J. M. J., 2009. Synthesis of furans, pyrroles and pyridazines by a ruthenium-catalysed isomerisation of alkynediols and in situ cyclisation. Tetrahedron, 65 (44), pp. 8981-8986.
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Alkyne-1,4-diols are readily available substrates which are isomerised to 1,4-diketones using Ru(PPh3)(3)(CO)H-2/xantphos as a catalyst. In situ cyclisation into furans, pyrroles and pyridazines has been achieved under suitable conditions. (C) 2009 Elsevier Ltd. All rights reserved.
|Creators||Pridmore, S. J., Slatford, P. A., Taylor, J. E., Whittlesey, M. K. and Williams, J. M. J.|
|Departments||Faculty of Science > Chemistry|
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