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Synthesis of furans, pyrroles and pyridazines by a ruthenium-catalysed isomerisation of alkynediols and in situ cyclisation


Reference:

Pridmore, S. J., Slatford, P. A., Taylor, J. E., Whittlesey, M. K. and Williams, J. M. J., 2009. Synthesis of furans, pyrroles and pyridazines by a ruthenium-catalysed isomerisation of alkynediols and in situ cyclisation. Tetrahedron, 65 (44), pp. 8981-8986.

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Official URL:

http://dx.doi.org/10.1016/j.tet.2009.06.108

Abstract

Alkyne-1,4-diols are readily available substrates which are isomerised to 1,4-diketones using Ru(PPh3)(3)(CO)H-2/xantphos as a catalyst. In situ cyclisation into furans, pyrroles and pyridazines has been achieved under suitable conditions. (C) 2009 Elsevier Ltd. All rights reserved.

Details

Item Type Articles
CreatorsPridmore, S. J., Slatford, P. A., Taylor, J. E., Whittlesey, M. K. and Williams, J. M. J.
DOI10.1016/j.tet.2009.06.108
DepartmentsFaculty of Science > Chemistry
RefereedYes
StatusPublished
ID Code17083

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