Synthesis and structural chemistry of metallo-xanthate anions (M = Zn, Sn, Bi)

Reference:

ur Rehman, A., Ali, S., Kociok-Kohn, G. and Molloy, K. C., 2009. Synthesis and structural chemistry of metallo-xanthate anions (M = Zn, Sn, Bi). Journal of Molecular Structure, 937 (1-3), pp. 56-60.

Related documents:

Official URL:

http://dx.doi.org/10.1016/j.molstruc.2009.08.012

Abstract

The structures of the metallo-xanthate anions [Zn(S2COR)(3)](-) (R = Et (1), Pr-i (2)), [Sn(S2COR)(3)](-) (R = Et (3), Pr-i (4)), and [Bi(S2COPri)(4)](-) (5) have been determined as their (Me4N](+) salts. The two zinc species differ in having either all SS bonded ligands (1) or both SS and S,O-ligation (2). The tin compounds are either monomeric (4) or weakly associated into dinners (3), while 5 adopts a monomeric dodecahedral structure. (C) 2009 Elsevier B.V. All rights reserved.

Export

Actions (login required)