An enantiopure pseudo-C-3-symmetric titanium triflate with propeller-like chirality as a catalyst for asymmetric sulfoxidation reactions

Reference:

Axe, P., Bull, S. D., Davidson, M. G., Jones, M. D., Robinson, D. E. J. E., Mitchell, W. L. and Warren, J. E., 2009. An enantiopure pseudo-C-3-symmetric titanium triflate with propeller-like chirality as a catalyst for asymmetric sulfoxidation reactions. Dalton Transactions, 2009 (46), pp. 10169-10171.

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Official URL:

http://dx.doi.org/10.1039/b918141p

Abstract

A chiral pseudo-C-3-symmetric titanium triflate that employs the point chirality of a single stereogenic centre to control the propeller chirality of its aryl rings has been used to catalyse an asymmetric sulfoxidation reaction.

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