Research

The reaction of tin(IV) iodide with phosphines: formation of new halotin anions


Reference:

Apostolico, L., Kociok-Kohn, G., Molloy, K. C., Blackman, C. S., Carmalt, C. J. and Parkin, I. P., 2009. The reaction of tin(IV) iodide with phosphines: formation of new halotin anions. Dalton Transactions, 47, pp. 10486-10494.

Related documents:

This repository does not currently have the full-text of this item.
You may be able to access a copy if URLs are provided below. (Contact Author)

Official URL:

http://dx.doi.org/10.1039/b917722a

Abstract

The reaction of SnI4 with each of a primary, secondary and tertiary phosphine has been investigated and in none of the cases are simple adducts formed. With Cy3P, [Cy3PI](+) salts of both [SnI3](-) (1) and [SnI5](-) (2) are isolated arising from reactions involving both reduction at tin and halogen transfer. With the secondary and primary amines Ph2PH and CyPH2, respectively, additional HI elimination reactions occur and the salts [Ph2PH2](+)(6)[Sn3I12](6-) (3), [Ph2PH2](+)(2)[SnI6](2-) (4) and [CyPH3](+)(2)[SnI4](2-) (5) have been isolated. Compounds 1-5 have been characterised crystallographically.

Details

Item Type Articles
CreatorsApostolico, L., Kociok-Kohn, G., Molloy, K. C., Blackman, C. S., Carmalt, C. J. and Parkin, I. P.
DOI10.1039/b917722a
DepartmentsFaculty of Science > Chemistry
RefereedYes
StatusPublished
ID Code17375

Export

Actions (login required)

View Item