Iron(0) tricarbonyl complexes of microbially derived cyclohexadiene ligands containing quaternary stereocenters
Reference:
Ali Khan, M., Mahon, M. F., Stewart, A. J. W. and Lewis, S. E., 2010. Iron(0) tricarbonyl complexes of microbially derived cyclohexadiene ligands containing quaternary stereocenters. Organometallics, 29 (1), pp. 199-204.
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Official URL:
http://dx.doi.org/10.1021/om9009069
Abstract
Tricarbonyliron(0) complexes of novel cyclohexadiene ligands possessing quaternary centers have been synthesized and characterized by H-1 and C-13 NMR and by X-ray crystallography. The ligands, which are derived Via all unusual microbial oxidation of benzoic acid, have been shown to undergo oxidative modification postcomplexation. The factors that influence facial discrimination upon complexation are discussed.
Details
| Item Type | Articles |
| Creators | Ali Khan, M., Mahon, M. F., Stewart, A. J. W. and Lewis, S. E. |
| DOI | 10.1021/om9009069 |
| Departments | Faculty of Science > Chemistry |
| Publisher Statement | Lewis_Organimetallics_29_1_199.pdf: This document is the Accepted Manuscript version of a Published Work that appeared in final form in Organometalics, copyright © American Chemical Society after peer review and technical editing by the publisher. To access the final edited and published work see http://dx.doi.org/10.1021/om9009069; Lewis_Organimetallics_29_1_199.doc: This document is the Accepted Manuscript version of a Published Work that appeared in final form in Organometalics, copyright © American Chemical Society after peer review and technical editing by the publisher. To access the final edited and published work see http://dx.doi.org/10.1021/om9009069; Lewis_Organometalics_2009.cif.txt: This document is the Accepted Manuscript version of a Published Work that appeared in final form in Organometalics, copyright © American Chemical Society after peer review and technical editing by the publisher. To access the final edited and published work see http://dx.doi.org/10.1021/om9009069 |
| Refereed | Yes |
| Status | Published |
| ID Code | 17648 |
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