Jones, M. D., Davidson, M. G. and Kociok-Kohn, G., 2010. New titanium and zirconium initiators for the production of polylactide. Polyhedron, 29 (2), pp. 697-700.
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Two new group 4 initiators based on N,N'-Bis(2-hydroxybenzyl)ethylenediamine have been prepared and fully characterised via multi-nuclear NMR spectroscopy and single crystal X-ray diffraction studies. The complexes have been tested for the production of polylactide. The phenolate ligand complexes to Ti(IV) to generate the beta-cis isomer in the solid-state. Whereas for Zr(IV) the isolated species (regardless of stoichiometery) is a diligated complex.
|Item Type ||Articles|
|Creators||Jones, M. D., Davidson, M. G. and Kociok-Kohn, G.|
|Departments||Faculty of Science > Chemistry|
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