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New titanium and zirconium initiators for the production of polylactide


Reference:

Jones, M. D., Davidson, M. G. and Kociok-Kohn, G., 2010. New titanium and zirconium initiators for the production of polylactide. Polyhedron, 29 (2), pp. 697-700.

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Official URL:

http://dx.doi.org/10.1016/j.poly.2009.10.007

Abstract

Two new group 4 initiators based on N,N'-Bis(2-hydroxybenzyl)ethylenediamine have been prepared and fully characterised via multi-nuclear NMR spectroscopy and single crystal X-ray diffraction studies. The complexes have been tested for the production of polylactide. The phenolate ligand complexes to Ti(IV) to generate the beta-cis isomer in the solid-state. Whereas for Zr(IV) the isolated species (regardless of stoichiometery) is a diligated complex.

Details

Item Type Articles
CreatorsJones, M. D., Davidson, M. G. and Kociok-Kohn, G.
DOI10.1016/j.poly.2009.10.007
DepartmentsFaculty of Science > Chemistry
RefereedYes
StatusPublished
ID Code18303

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