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Molecular and supramolecular diversity displayed by dienone-ether macrocycles


Reference:

Higham, L. T., Scott, J. L. and Strauss, C. R., 2010. Molecular and supramolecular diversity displayed by dienone-ether macrocycles. Crystal Growth and Design, 10 (5), pp. 2409-2420.

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Official URL:

http://dx.doi.org/10.1021/cg100235x

Abstract

Dienone-ether macrocycles (DEMs) represent a new class of supramolecular building blocks for the preparation of crystalline materials with potentially diverse applications. A modular, building block approach to the synthesis employs a range of linked aryl aldehydes and cyclic ketones. Consequently, the structures of DEMs can be tuned with regard to size and shape and the incorporation of functional elements for specific purposes. Fourteen examples are presented, illustrating the diversity of DEMs accessible by this approach. The effect of molecular structure on conformation, supramolecular inclusion, and crystal packing is discussed.

Details

Item Type Articles
CreatorsHigham, L. T., Scott, J. L. and Strauss, C. R.
DOI10.1021/cg100235x
DepartmentsFaculty of Science > Chemistry
RefereedYes
StatusPublished
ID Code18942

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