α-Fluorination of β-ketosulfones by Selectfluor™ F–TEDA–BF4
Loghmani-Khouzani, H., Poorheravi, M. R., Sadeghi, M. M. M., Caggiano, L. and Jackson, R. F. W., 2008. α-Fluorination of β-ketosulfones by Selectfluor™ F–TEDA–BF4. Tetrahedron, 64 (30-31), pp. 7419-7425.
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Attempted fluorination of β-ketosulfides using Selectfluor™ resulted only in the isolation of the corresponding diaryl disulfides, presumed to arise by decomposition of an unstable fluorinated intermediate. However, fluorination of β-ketosulfones using Selectfluor™ under anhydrous conditions does allow the isolation of both mono-and difluorinated products in moderate to good yields.
|Creators||Loghmani-Khouzani, H., Poorheravi, M. R., Sadeghi, M. M. M., Caggiano, L. and Jackson, R. F. W.|
|Departments||Faculty of Science > Pharmacy & Pharmacology|
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