Research

Highly regioselective decarboxylative Claisen rearrangement reactions of diallyl 2-sulfonylmalonates


Reference:

Craig, D., Lansdell, M. I. and Lewis, S. E., 2007. Highly regioselective decarboxylative Claisen rearrangement reactions of diallyl 2-sulfonylmalonates. Tetrahedron Letters, 48 (44), pp. 7861-7864.

Related documents:

[img]
Preview
PDF (Lewis_Tetrahedron-Letters_2007_48_44_7861.pdf) - Requires a PDF viewer such as GSview, Xpdf or Adobe Acrobat Reader
Download (599kB) | Preview

    Official URL:

    http://dx.doi.org/10.1016/j.tetlet.2007.08.130

    Abstract

    The decarboxylative Claisen rearrangement of a range of substituted diallyl 2-sulfonylmalonates is described. The substrates are made by C-carboxylation of the corresponding allyl sulfonylacetates with allyl para-nitrophenyl carbonates. The reactions display a high degree of regioselectivity, with allylic substituents possessing electron-rich substituents at the allyl three-position rearranging preferentially.

    Details

    Item Type Articles
    CreatorsCraig, D., Lansdell, M. I. and Lewis, S. E.
    DOI10.1016/j.tetlet.2007.08.130
    DepartmentsFaculty of Science > Chemistry
    Publisher StatementLewis_Tetrahedron-Letters_2007_48_44_7861.pdf: NOTICE: this is the author’s version of a work that was accepted for publication in Tetrahedron Letters. Changes resulting from the publishing process, such as peer review, editing, corrections, structural formatting, and other quality control mechanisms may not be reflected in this document. Changes may have been made to this work since it was submitted for publication. A definitive version was subsequently published in Tetrahedron Letters Volume 48, Issue 44, 29 October 2007, Pages 7861-7864, DOI 10.1016/j.tetlet.2007.08.130; Lewis_Tetrahedron-Letters_2007_48_44_7861.doc: NOTICE: this is the author’s version of a work that was accepted for publication in Tetrahedron Letters. Changes resulting from the publishing process, such as peer review, editing, corrections, structural formatting, and other quality control mechanisms may not be reflected in this document. Changes may have been made to this work since it was submitted for publication. A definitive version was subsequently published in Tetrahedron Letters Volume 48, Issue 44, 29 October 2007, Pages 7861-7864, DOI 10.1016/j.tetlet.2007.08.130
    RefereedYes
    StatusPublished
    ID Code19933

    Export

    Actions (login required)

    View Item

    Document Downloads

    More statistics for this item...