Dipyridyl beta-diketonate complexes: versatile polydentate metalloligands for metal-organic frameworks and hydrogen-bonded networks

Reference:

Burrows, A. D., Frost, C. G., Mahon, M. F., Raithby, P. R., Renouf, C. L., Richardson, C. and Stevenson, A., 2010. Dipyridyl beta-diketonate complexes: versatile polydentate metalloligands for metal-organic frameworks and hydrogen-bonded networks. Chemical Communications, 46 (28), pp. 5067-5069.

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Official URL:

http://dx.doi.org/10.1039/c0cc00646g

Abstract

The Group 13 metal complexes [M(L-2)(3)], where M is Al or Ga and L-2 is 1,3-di(4-pyridyl)-1,3-propanedionato, are hexatopic metalloligands that have been used to prepare mixed-metalorganic frameworks containing interpenetrated primitive cubic networks. In contrast, the europium complex [Eu(HL2)(3)-(H2L2)]Cl-4 center dot EtOH forms a hydrogen-bonded network following partial protonation of the pyridyl groups.

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