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Solid state interconversion of cages and coordination networks via conformational change of a semi-rigid ligand


Reference:

Burrows, A. D., Frost, C. G., Mahon, M. F., Raithby, P. R., Richardson, C. and Stevenson, A., 2010. Solid state interconversion of cages and coordination networks via conformational change of a semi-rigid ligand. Chemical Communications, 46 (28), pp. 5064-5066.

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    Official URL:

    http://dx.doi.org/10.1039/c0cc00826e

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    Abstract

    The reaction of silver(I) perchlorate with the semi-rigid ligand 1,4-bis((3,5-dimethylisoxazol-4-yl)methyl) benzene (bisox) in methanol gives a triply-interpenetrated sheet structure, but a structure containing both interpenetrated sheets and Ag-2(bisox)(3) cages is formed on recrystallisation from acetonitrile-diethyl ether. Rearrangement of the cages into sheets occurs on heating under vacuum, a process which involves a solid state change in conformation of the bisox ligands.

    Details

    Item Type Articles
    CreatorsBurrows, A. D., Frost, C. G., Mahon, M. F., Raithby, P. R., Richardson, C. and Stevenson, A.
    DOI10.1039/c0cc00826e
    Related URLs
    URLURL Type
    http://www.scopus.com/inward/record.url?eid=2-s2.0-77954574128&partnerID=8YFLogxKUNSPECIFIED
    DepartmentsFaculty of Science > Chemistry
    RefereedYes
    StatusPublished
    ID Code20133

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