Exploring rhodium-catalysed conjugate addition of chiral alkenylboronates using chiral olefin ligands
Reference:
Frost, C. G., Edwards, H. J., Penrose, S. D. and Gleave, R., 2010. Exploring rhodium-catalysed conjugate addition of chiral alkenylboronates using chiral olefin ligands. Synthesis, 2010 (19), pp. 3243-3247.
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Official URL:
http://dx.doi.org/10.1055/s-0030-1258203
Abstract
The rhodium-catalysed addition of chiral alkenylboron reagents to prochiral alpha,beta-unsaturated carbonyl acceptors are demonstrated to proceed under ligand control. The highest activities were obtained with chiral olefin ligands and the configuration of the new stereocentre can be predicted by using established models.
Details
| Item Type | Articles |
| Creators | Frost, C. G., Edwards, H. J., Penrose, S. D. and Gleave, R. |
| DOI | 10.1055/s-0030-1258203 |
| Departments | Faculty of Science > Chemistry |
| Refereed | Yes |
| Status | Published |
| ID Code | 21132 |
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