Research

Exploring rhodium-catalysed conjugate addition of chiral alkenylboronates using chiral olefin ligands


Reference:

Frost, C. G., Edwards, H. J., Penrose, S. D. and Gleave, R., 2010. Exploring rhodium-catalysed conjugate addition of chiral alkenylboronates using chiral olefin ligands. Synthesis, 2010 (19), pp. 3243-3247.

Related documents:

This repository does not currently have the full-text of this item.
You may be able to access a copy if URLs are provided below. (Contact Author)

Official URL:

http://dx.doi.org/10.1055/s-0030-1258203

Abstract

The rhodium-catalysed addition of chiral alkenylboron reagents to prochiral alpha,beta-unsaturated carbonyl acceptors are demonstrated to proceed under ligand control. The highest activities were obtained with chiral olefin ligands and the configuration of the new stereocentre can be predicted by using established models.

Details

Item Type Articles
CreatorsFrost, C. G., Edwards, H. J., Penrose, S. D. and Gleave, R.
DOI10.1055/s-0030-1258203
DepartmentsFaculty of Science > Chemistry
RefereedYes
StatusPublished
ID Code21132

Export

Actions (login required)

View Item