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An expedient asymmetric synthesis of N-protected (S,S)-2-Aminomethyl-1-cyclopropanecarboxylic acid


Reference:

Aitken, D. J., Bull, S. D., Davies, I. R., Drouin, L., Ollivier, J. and Peed, J., 2010. An expedient asymmetric synthesis of N-protected (S,S)-2-Aminomethyl-1-cyclopropanecarboxylic acid. Synlett, 18, pp. 2729-2732.

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Official URL:

http://dx.doi.org/10.1055/s-0030-1258814

Abstract

An enantioselective synthesis of a N-Boc-protected trans-cyclopropane gamma-amino acid is reported. The key chiral aldehyde intermediate is prepared in enantiomerically pure form using a three-step aldol-cyclopropanation-retro-aldol protocol.

Details

Item Type Articles
CreatorsAitken, D. J., Bull, S. D., Davies, I. R., Drouin, L., Ollivier, J. and Peed, J.
DOI10.1055/s-0030-1258814
Uncontrolled Keywordsenantioselectivity, carbocycle, asymmetric synthesis, aldol reaction, amino acids, chiral auxiliary
DepartmentsFaculty of Science > Chemistry
RefereedYes
StatusPublished
ID Code21603

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