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Catalytic acylation of amines with aldehydes or aldoximes


Reference:

Allen, C. L., Davulcu, S. and Williams, J., 2010. Catalytic acylation of amines with aldehydes or aldoximes. Organic Letters, 12 (22), pp. 5096-5099.

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Official URL:

http://dx.doi.org/10.1021/ol101978h

Abstract

The simple nickel salt NiCl2 center dot 6H(2)O catalyzes the coupling of aldoximes with amines to give secondary or tertiary amide products. The aldoxime can be prepared in situ from the corresponding aldehyde. The use of O-18-labeled oximes has allowed insight into the mechanism of this reaction.

Details

Item Type Articles
CreatorsAllen, C. L., Davulcu, S. and Williams, J.
DOI10.1021/ol101978h
DepartmentsFaculty of Science > Chemistry
RefereedYes
StatusPublished
ID Code22135

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