Accessing the antipodal series in microbial arene oxidation: a novel diene rearrangement induced by tricarbonyliron(0) complexation
Reference:
Ali Khan, M., Lowe, J. P., Johnson, A. L., Stewart, A. J. W. and Lewis, S. E., 2011. Accessing the antipodal series in microbial arene oxidation: a novel diene rearrangement induced by tricarbonyliron(0) complexation. Chemical Communications, 47 (1), pp. 215-217.
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Official URL:
http://dx.doi.org/10.1039/c0cc01169j
Abstract
A cyclohexadiene ligand prepared by microbial arene 1,2-dihydroxylation undergoes spontaneous rearrangement upon complexation to tricarbonyliron(0). Subsequent iron removal affords a novel route to formal arene 2,3-dihydroxylation products enantiomeric to those obtainable by direct microbial arene oxidation.
Details
| Item Type | Articles |
| Creators | Ali Khan, M., Lowe, J. P., Johnson, A. L., Stewart, A. J. W. and Lewis, S. E. |
| DOI | 10.1039/c0cc01169j |
| Departments | Faculty of Science > Chemistry |
| Refereed | Yes |
| Status | Published |
| ID Code | 22224 |
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