Structure of eutectic liquids in the Au-Si, Au-Ge, and Ag-Ge binary systems by neutron diffraction

Reference:

Chirawatkul, P., Zeidler, A., Salmon, P. S., Takeda, S., Kawakita, Y., Usuki, T. and Fischer, H., 2011. Structure of eutectic liquids in the Au-Si, Au-Ge, and Ag-Ge binary systems by neutron diffraction. Physical Review B, 83 (1), 014203.

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Official URL:

http://dx.doi.org/10.1103/PhysRevB.83.014203

Abstract

Neutron diffraction was used to investigate the structure of the liquid alloys Au0.81Si0.19, Au0.72Ge0.28, and Ag0.74Ge0.26 with composition at or near the eutectic. For a given alloy, the measured pair distribution function is described over a wide range of distances, from 5–6 Å to beyond 20 Å, by an exponentially damped oscillatory function with a decay length and wavelength of oscillation related to the half-width at half-maximum of the principal peak in the total structure factor and to the position of this peak, respectively. This behavior is expected from solutions of the Ornstein-Zernike equations for simple pair potentials. There is no need to invoke the existence of a fractal network, as suggested by a recent analysis of the diffraction patterns measured for amorphous metallic alloys, to account for the experimental results. A reconsideration of the diffraction data for these amorphous alloys points to the same conclusion.

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