Selective incorporation of functional dicarboxylates into zinc metal-organic frameworks
Burrows, A. D., Fisher, L. C., Richardson, C. and Rigby, S. P., 2011. Selective incorporation of functional dicarboxylates into zinc metal-organic frameworks. Chemical Communications, 47 (12), pp. 3380-3382.
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Zinc(II) nitrate reacts with different ratios of 1,4-benzenedicarboxylic acid (H(2)bdc) and 2-halo-1,4-benzenedicarboxylic acid (H(2)bdc-X, X = Br or I) to give [Zn4O(bdc)(3-x)(bdc-X)(x)], in which preferential incorporation of bdc is observed. The selective incorporation is related to crystal growth rates, and the proportion of incorporated bdc-X rises with increasing reaction time.
|Creators||Burrows, A. D., Fisher, L. C., Richardson, C. and Rigby, S. P.|
|Departments||Faculty of Engineering & Design > Chemical Engineering|
Faculty of Science > Chemistry
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