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Selective incorporation of functional dicarboxylates into zinc metal-organic frameworks


Reference:

Burrows, A. D., Fisher, L. C., Richardson, C. and Rigby, S. P., 2011. Selective incorporation of functional dicarboxylates into zinc metal-organic frameworks. Chemical Communications, 47 (12), pp. 3380-3382.

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Official URL:

http://dx.doi.org/10.1039/c1cc10143a

Abstract

Zinc(II) nitrate reacts with different ratios of 1,4-benzenedicarboxylic acid (H(2)bdc) and 2-halo-1,4-benzenedicarboxylic acid (H(2)bdc-X, X = Br or I) to give [Zn4O(bdc)(3-x)(bdc-X)(x)], in which preferential incorporation of bdc is observed. The selective incorporation is related to crystal growth rates, and the proportion of incorporated bdc-X rises with increasing reaction time.

Details

Item Type Articles
CreatorsBurrows, A. D., Fisher, L. C., Richardson, C. and Rigby, S. P.
DOI10.1039/c1cc10143a
DepartmentsFaculty of Engineering & Design > Chemical Engineering
Faculty of Science > Chemistry
RefereedYes
StatusPublished
ID Code23233

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