Suppression of Schlenk equilibration and heavier alkaline earth alkyl catalysis: A dearomatization strategy
Reference:
Arrowsmith, M., Hill, M. S. and Kociok-Kohn, G., 2011. Suppression of Schlenk equilibration and heavier alkaline earth alkyl catalysis: A dearomatization strategy. Organometallics, 30 (6), pp. 1291-1294.
Related documents:
This repository does not currently have the full-text of this item.You may be able to access a copy if URLs are provided below. (Contact Author)
Official URL:
http://dx.doi.org/10.1021/om200028m
Abstract
Reaction of a bis(imino)acenapthene with the heavier alkaline earth dialkyls [Ae{CH(SiMe3)(2)}(2)(THF)(2)] (Ac = Mg, Ca, Sr) results in deromatization of the aromatic ligand and the isolation of heteroleptic alkyl species which show unprecedented stability toward Schlenk-type redistribution and exceptional catalytic activity toward the hydroamination of aminoalkeries.
Details
| Item Type | Articles |
| Creators | Arrowsmith, M., Hill, M. S. and Kociok-Kohn, G. |
| DOI | 10.1021/om200028m |
| Departments | Faculty of Science > Chemistry |
| Refereed | Yes |
| Status | Published |
| ID Code | 23476 |
Export
Actions (login required)
| View Item |
