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Suppression of Schlenk equilibration and heavier alkaline earth alkyl catalysis: A dearomatization strategy


Reference:

Arrowsmith, M., Hill, M. S. and Kociok-Kohn, G., 2011. Suppression of Schlenk equilibration and heavier alkaline earth alkyl catalysis: A dearomatization strategy. Organometallics, 30 (6), pp. 1291-1294.

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Official URL:

http://dx.doi.org/10.1021/om200028m

Abstract

Reaction of a bis(imino)acenapthene with the heavier alkaline earth dialkyls [Ae{CH(SiMe3)(2)}(2)(THF)(2)] (Ac = Mg, Ca, Sr) results in deromatization of the aromatic ligand and the isolation of heteroleptic alkyl species which show unprecedented stability toward Schlenk-type redistribution and exceptional catalytic activity toward the hydroamination of aminoalkeries.

Details

Item Type Articles
CreatorsArrowsmith, M., Hill, M. S. and Kociok-Kohn, G.
DOI10.1021/om200028m
DepartmentsFaculty of Science > Chemistry
RefereedYes
StatusPublished
ID Code23476

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