Photostimulated reduction processes in a titania hybrid metal-organic framework
Reference:
Walsh, A. and Catlow, C. R. A., 2010. Photostimulated reduction processes in a titania hybrid metal-organic framework. ChemPhysChem, 11 (11), pp. 2341-2344.
Related documents:
This repository does not currently have the full-text of this item.You may be able to access a copy if URLs are provided below. (Contact Author)
Official URL:
http://dx.doi.org/10.1002/cphc.201000306
Abstract
Lights, camera, action! A hybrid material derived from TiO2 is found to have remarkable defect chemistry: optical excitations larger than the band gap have sufficient energy to reduce titanium, accompanied by oxygen loss (see figure). New states introduced in the electronic gap are responsible for the material′s photochromicity. The future looks bright for photoactive metal–organic frameworks.
Details
| Item Type | Articles |
| Creators | Walsh, A.and Catlow, C. R. A. |
| DOI | 10.1002/cphc.201000306 |
| Uncontrolled Keywords | electrode, semiconductor, cells, metal-organic frameworks, wave basis-set, titanium, photochemistry, hybrid materials, total-energy calculations, reduction |
| Departments | Faculty of Science > Chemistry |
| Refereed | Yes |
| Status | Published |
| ID Code | 23972 |
Export
Actions (login required)
| View Item |
