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Photostimulated reduction processes in a titania hybrid metal-organic framework


Reference:

Walsh, A. and Catlow, C. R. A., 2010. Photostimulated reduction processes in a titania hybrid metal-organic framework. ChemPhysChem, 11 (11), pp. 2341-2344.

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Official URL:

http://dx.doi.org/10.1002/cphc.201000306

Abstract

Lights, camera, action! A hybrid material derived from TiO2 is found to have remarkable defect chemistry: optical excitations larger than the band gap have sufficient energy to reduce titanium, accompanied by oxygen loss (see figure). New states introduced in the electronic gap are responsible for the material′s photochromicity. The future looks bright for photoactive metal–organic frameworks.

Details

Item Type Articles
CreatorsWalsh, A.and Catlow, C. R. A.
DOI10.1002/cphc.201000306
Uncontrolled Keywordselectrode, semiconductor, cells, metal-organic frameworks, wave basis-set, titanium, photochemistry, hybrid materials, total-energy calculations, reduction
DepartmentsFaculty of Science > Chemistry
RefereedYes
StatusPublished
ID Code23972

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