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Ion Pair-Driven Heterodimeric Capsule Based on Boronate Esterification: Construction and the Dynamic Behavior


Reference:

Kataoka, K., James, T. D. and Kubo, Y., 2007. Ion Pair-Driven Heterodimeric Capsule Based on Boronate Esterification: Construction and the Dynamic Behavior. Journal of the American Chemical Society, 129 (49), pp. 15126-15127.

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Official URL:

http://dx.doi.org/10.1021/ja076792f

Abstract

We describe the ion pair-driven heterodimeric capsule formation of a cyclotricatechylene 1 and a boronic acid-appended hexahomotrioxacalix[3]arene 2. Although I does not interact with 2 in a protic solution, in the presence of Et4NAcO quantitative formation of a heterodimeric capsule via boronate esterification was observed in the NMR, a direct result of anion-induced boronate ester formation and the Et4N+ template. Reversible boronate esterification allowed us to selectively control capsule assembly using pH switching.

Details

Item Type Articles
CreatorsKataoka, K., James, T. D. and Kubo, Y.
DOI10.1021/ja076792f
DepartmentsFaculty of Science > Chemistry
RefereedYes
StatusPublished
ID Code24586

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