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Synthesis and structural characterisation of the first bis(bora)calixarene: a selective, bidentate, fluorescent fluoride sensor


Reference:

Arimori, S., Davidson, M. D., Fyles, T. M., Hibbert, T. G., James, T. D. and Kociok-Kohn, G. I., 2004. Synthesis and structural characterisation of the first bis(bora)calixarene: a selective, bidentate, fluorescent fluoride sensor. Chemical Communications, 14, pp. 1640-1641.

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Official URL:

http://dx.doi.org/10.1039/b404937c

Abstract

A bis(bora) calixarene, 3, the first lower-rim boron derivatised calixarene to be structurally characterised, is synthesised by the reaction of PhBCl2 with 4-tert-butylcalix[4] arene, and is demonstrated to be a sensitive and selective fluorescent fluoride sensor.

Details

Item Type Articles
CreatorsArimori, S., Davidson, M. D., Fyles, T. M., Hibbert, T. G., James, T. D. and Kociok-Kohn, G. I.
DOI10.1039/b404937c
DepartmentsFaculty of Science > Chemistry
RefereedYes
StatusPublished
ID Code24635
Additional InformationElectronic supplementary information (ESI) available: synthetic and spectroscopic details for the preparation of 3; details of the fluorescence titration of 3 with F? including details on the procedure used for calculation of binding constants; and details of the crystal structure refinement. See http://www.rsc.org/suppdata/cc/b4/b404937c/

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