Synthesis and structural characterisation of the first bis(bora)calixarene: a selective, bidentate, fluorescent fluoride sensor
Reference:
Arimori, S., Davidson, M. D., Fyles, T. M., Hibbert, T. G., James, T. D. and Kociok-Kohn, G. I., 2004. Synthesis and structural characterisation of the first bis(bora)calixarene: a selective, bidentate, fluorescent fluoride sensor. Chemical Communications, 14, pp. 1640-1641.
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Official URL:
http://dx.doi.org/10.1039/b404937c
Abstract
A bis(bora) calixarene, 3, the first lower-rim boron derivatised calixarene to be structurally characterised, is synthesised by the reaction of PhBCl2 with 4-tert-butylcalix[4] arene, and is demonstrated to be a sensitive and selective fluorescent fluoride sensor.
Details
| Item Type | Articles |
| Creators | Arimori, S., Davidson, M. D., Fyles, T. M., Hibbert, T. G., James, T. D. and Kociok-Kohn, G. I. |
| DOI | 10.1039/b404937c |
| Departments | Faculty of Science > Chemistry |
| Refereed | Yes |
| Status | Published |
| ID Code | 24635 |
| Additional Information | Electronic supplementary information (ESI) available: synthetic and spectroscopic details for the preparation of 3; details of the fluorescence titration of 3 with F? including details on the procedure used for calculation of binding constants; and details of the crystal structure refinement. See http://www.rsc.org/suppdata/cc/b4/b404937c/ |
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