Research

Proton-driven switching between receptors for C60 and C70


Reference:

Stefankiewicz, A. R., Tamanini, E., Pantos, G. D. and Sanders, J. K. M., 2011. Proton-driven switching between receptors for C60 and C70. Angewandte Chemie-International Edition, 50 (25), pp. 5725-5728.

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Official URL:

http://dx.doi.org/10.1002/anie.201100806

Abstract

Buckybinding: The selective binding of either C60 and C 70 in a mixture of the two fullerenes occurs by proton-induced, reversible, and controllable morphological switching between receptors for different fullerenes (see picture). Using hydrogen bonding as the exchange reaction, the response of the naphthalenediimide (NDI) building blocks to the presence of fullerene guests depends on the concentration of protons as a third component.

Details

Item Type Articles
CreatorsStefankiewicz, A. R., Tamanini, E., Pantos, G. D. and Sanders, J. K. M.
DOI10.1002/anie.201100806
DepartmentsFaculty of Science > Chemistry
RefereedYes
StatusPublished
ID Code24656

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