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Sodium Trihydrogen-1,4-Benzenediphosphonate: An Extended Coordination Network


Reference:

Ayi, A. A., Burrows, A. D., Mahon, M. F. and Pop, V. M., 2011. Sodium Trihydrogen-1,4-Benzenediphosphonate: An Extended Coordination Network. Journal of Chemical Crystallography, 41 (8), pp. 1165-1168.

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    Official URL:

    http://dx.doi.org/10.1007/s10870-011-0064-0

    Abstract

    Crystals of sodium trihydrogen-1,4-benzenediphosphonate, Na[H(3)bdp], were prepared from the addition of aqueous sodium hydroxide to an acidified solution of 1,4-benzenediphosphonic acid (H(4)bdp). These were shown by X-ray crystallography to crystallize in the space group P (1) over bar, with cell parameters a = 5.7500(3) , b = 7.9180(5) , c = 10.4420(6) , alpha = 80.398(3)A degrees, beta A = 76.844(4)A degrees and gamma A = 81.389(4)A degrees. The crystal structure revealed that the title compound forms a coordination network in which sodium-phosphonate sheets are pillared by the benzene rings into a three-dimensional structure.

    Details

    Item Type Articles
    CreatorsAyi, A. A., Burrows, A. D., Mahon, M. F. and Pop, V. M.
    DOI10.1007/s10870-011-0064-0
    Uncontrolled Keywordssodium salts, coordination networks, phosphonates, coordination polymers
    DepartmentsFaculty of Science > Chemistry
    Publisher StatementBurrows_JCC_2011_41_8_1165.pdf: The original publication is available at www.springerlink.com
    RefereedYes
    StatusPublished
    ID Code25244

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