Structure, reactivity, and computational studies of a novel ruthenium hydrogen sulfide dihydride complex

Reference:

Chatwin, S. L., Diggle, R. A., Jazzar, R. F. R., Macgregor, S. A., Mahon, M. F. and Whittlesey, M. K., 2003. Structure, reactivity, and computational studies of a novel ruthenium hydrogen sulfide dihydride complex. Inorganic Chemistry, 42 (24), pp. 7695-7697.

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Abstract

Addition of 1 atm of H2S to [Ru(IMeS)(2)(CO)(EtOH)H-2] (IMes = 1,3-bis(2,4,6-trimethylphenyl)imidazol-2-ylidene) affords the air-stable hydrogen sulfide dihydride complex, [Ru(IMeS)(2)(CO)(H2S)H-2] 2. Treatment of 2 with excess H2S leads to formation of the 16-electron bis-hydrosulfido complex, [Ru(IMeS)(2)(CO)(SH)(2)] 3. Preliminary studies show that 3 reacts with both H-2 and CO in solution as well as in the solid state. Both 2 and 3 have been structurally characterized.

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