N-Aryl stilbazolium dyes as sensitizers for solar cells
Blackburn, O. A., Coe, B. J., Hahn, V., Helliwell, M., Raftery, J., Ta, Y. T., Peter, L. M., Wang, H., Anta, J. A. and Guillen, E., 2012. N-Aryl stilbazolium dyes as sensitizers for solar cells. Dyes and Pigments, 92 (1), pp. 766-777.
Related documents:This repository does not currently have the full-text of this item.
You may be able to access a copy if URLs are provided below. (Contact Author)
Eight new N-arylstilbazolium chromophores with electron donating -NR 2 (R = Me or Ph) substituents have been synthesized via Knoevenagel condensations and isolated as their PF6- salts. These compounds have been characterized by using various techniques including 1H NMR and IR spectroscopies and electrospray mass spectrometry. UV-vis absorption spectra recorded in acetonitrile are dominated by intense, low energy → (*) intramolecular charge-transfer (ICT) bands, and replacing Me with Ph increases the ICT energies. Cyclic voltammetric studies show irreversible reduction processes, together with oxidation waves that are irreversible for R = Me, but reversible for R = Ph. Single crystal X-ray structures have been determined for three of the methyl ester-substituted stilbazolium salts and for the Cl- salts of their picolinium precursors. Time-dependent density functional theory calculations afford reasonable predictions of ICT energies, but greater rigour is necessary for -NPh2 derivatives. The four new acid-functionalized dyes give moderate sensitization efficiencies (ca. 0.2%) when using TiO2-based photoanodes, with relatively higher values for R = Ph vs Me, while larger efficiencies (up to 0.8%) are achieved with ZnO substrates. 2011 Elsevier Ltd. All rights reserved.
|Creators||Blackburn, O. A., Coe, B. J., Hahn, V., Helliwell, M., Raftery, J., Ta, Y. T., Peter, L. M., Wang, H., Anta, J. A. and Guillen, E.|
|Departments||Faculty of Science > Chemistry|
Actions (login required)