Research

Supramolecular chemistry of monochiral naphthalenediimides


Reference:

Anderson, T. W., Pantos, G. D. and Sanders, J. K. M., 2011. Supramolecular chemistry of monochiral naphthalenediimides. Organic and Biomolecular Chemistry, 9 (21), pp. 7547-7553.

Related documents:

This repository does not currently have the full-text of this item.
You may be able to access a copy if URLs are provided below. (Contact Author)

Official URL:

http://dx.doi.org/10.1039/c1ob06147j

Abstract

Three new N-desymmetrised naphthalenediimides (NDIs) are described, each containing one chiral and one achiral centre. The ability of such 'monochiral' NDIs to self-assemble into hydrogen-bonded helical nanotubes, to act as a sergeant in a 'sergeants-and-soldiers' system and to form a hexameric receptor for C70 was examined. Small differences at the achiral centre were found to have significant effects on the supramolecular properties of the NDI. All three new NDIs form nanotubes that bind C60, but with different efficiencies, and one is a better sergeant than any of the dichiral NDIs investigated to date.

Details

Item Type Articles
CreatorsAnderson, T. W., Pantos, G. D. and Sanders, J. K. M.
DOI10.1039/c1ob06147j
DepartmentsFaculty of Science > Chemistry
RefereedYes
StatusPublished
ID Code27142

Export

Actions (login required)

View Item