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Crystal structures and magnetic properties of a sterically encumbered dithiadiazolyl radical, 2,4,6-(F3C)(3)C6H2CNSSN center dot


Reference:

Alberola, A., Clarke, C. S., Haynes, D. A., Pascu, S. I. and Rawson, J. M., 2005. Crystal structures and magnetic properties of a sterically encumbered dithiadiazolyl radical, 2,4,6-(F3C)(3)C6H2CNSSN center dot. Chemical Communications, 2005 (37), pp. 4726-4728.

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Official URL:

http://dx.doi.org/10.1039/b508371k

Abstract

The sterically protected dithiadiazolyl radical (F3C)(3)C6H2-CNSSNcenter dot (1) crystallises in two polymorphs: 1 alpha, comprised of monomeric units and 1 beta, containing a mixture of both pi*-pi* dimers and S = 1/2 monomers; whilst both polymorphs exhibit similar structure-directing motifs, the variation in packing leads to different magnetic behaviour.

Details

Item Type Articles
CreatorsAlberola, A., Clarke, C. S., Haynes, D. A., Pascu, S. I. and Rawson, J. M.
DOI10.1039/b508371k
DepartmentsFaculty of Science > Chemistry
RefereedYes
StatusPublished
ID Code27328

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