Crystal structures and magnetic properties of a sterically encumbered dithiadiazolyl radical, 2,4,6-(F3C)(3)C6H2CNSSN center dot
Reference:
Alberola, A., Clarke, C. S., Haynes, D. A., Pascu, S. I. and Rawson, J. M., 2005. Crystal structures and magnetic properties of a sterically encumbered dithiadiazolyl radical, 2,4,6-(F3C)(3)C6H2CNSSN center dot. Chemical Communications, 2005 (37), pp. 4726-4728.
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Official URL:
http://dx.doi.org/10.1039/b508371k
Abstract
The sterically protected dithiadiazolyl radical (F3C)(3)C6H2-CNSSNcenter dot (1) crystallises in two polymorphs: 1 alpha, comprised of monomeric units and 1 beta, containing a mixture of both pi*-pi* dimers and S = 1/2 monomers; whilst both polymorphs exhibit similar structure-directing motifs, the variation in packing leads to different magnetic behaviour.
Details
| Item Type | Articles |
| Creators | Alberola, A., Clarke, C. S., Haynes, D. A., Pascu, S. I. and Rawson, J. M. |
| DOI | 10.1039/b508371k |
| Departments | Faculty of Science > Chemistry |
| Refereed | Yes |
| Status | Published |
| ID Code | 27328 |
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