Research

Synthesis of a new bidentate ferrocenyl N-heterocyclic carbene ligand precursor and the palladium (II) complex trans- PdCl2(C over cap fc over cap C) , where (C over cap fc over cap C)=1,1 '-di-tert-butyl-3,3 ' (1,1 '-dimethyleneferrocenyl)-diimidazol-2-ylidene


Reference:

Coleman, K. S., Turberville, S., Pascu, S. I. and Green, M. L. H., 2005. Synthesis of a new bidentate ferrocenyl N-heterocyclic carbene ligand precursor and the palladium (II) complex trans- PdCl2(C over cap fc over cap C) , where (C over cap fc over cap C)=1,1 '-di-tert-butyl-3,3 ' (1,1 '-dimethyleneferrocenyl)-diimidazol-2-ylidene. Journal of Organometallic Chemistry, 690 (3), pp. 653-658.

Related documents:

This repository does not currently have the full-text of this item.
You may be able to access a copy if URLs are provided below.

Official URL:

http://dx.doi.org/10.1016/j.jorganchem.2004.10.019

Abstract

A new ferrocenyl-N-heterocyclic carbene ligand precursor 1,1'-bis[(1-tert-butylimidazolium)-3-methyl]ferrocene dichloride has been synthesised and structurally characterised. The imidazolium salt was readily deprotonated in situ with KN(SiMe3)(2) and reacted with [PdCl2 (cod)] to afford the structurally characterised palladium (II) complex trans-[PdCl2(CfcC)], where (cod) = 1,5-cyclooctadiene and (CfcC) = 1,1'-di-tert-butyl-3,3'-(1,1'-dimethyleneferrocenyl)-diimidazol-2-yliden e.

Details

Item Type Articles
CreatorsColeman, K. S., Turberville, S., Pascu, S. I. and Green, M. L. H.
DOI10.1016/j.jorganchem.2004.10.019
DepartmentsFaculty of Science > Chemistry
RefereedYes
StatusPublished
ID Code27339

Export

Actions (login required)

View Item