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Liquid | liquid electrochemical bicarbonate and carbonate capture facilitated by boronic acids


Reference:

Collins, A. M., Watkins, J. D., Katif, N., Huang, Y. J., Jiang, Y. B., James, T. D., Bull, S. D. and Marken, F., 2011. Liquid | liquid electrochemical bicarbonate and carbonate capture facilitated by boronic acids. Chemical Communications, 47 (43), pp. 12002-12004.

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Official URL:

http://dx.doi.org/10.1039/c1cc15211d

Abstract

Reversible bicarbonate and carbonate liquid|liquid ion transfer processes from aqueous solution into an organic 4-(3-phenylpropyl)pyridine phase are driven electrochemically with TPPMn(III/II) and shown to be facilitated over a wide pH range by 2-naphthylboronic acid (bicarbonate transfer potential -0.08 V vs. SCE; binding constant K(AB) = 10 2 mol(-1) dm(3) and carbonate dianion transfer potential 0.07 V vs. SCE; binding constant K(AB2) = 2 x 10(10) mol(-2) dm(6)).

Details

Item Type Articles
CreatorsCollins, A. M., Watkins, J. D., Katif, N., Huang, Y. J., Jiang, Y. B., James, T. D., Bull, S. D. and Marken, F.
DOI10.1039/c1cc15211d
DepartmentsFaculty of Science > Chemistry
RefereedYes
StatusPublished
ID Code27442

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