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Group 4 initiators for the stereoselective ROP of rac-β-butyrolactone and its copolymerization with rac-lactide


Reference:

Jeffery, B. J., Whitelaw, E. L., Garcia-Vivo, D., Stewart, J. A., Mahon, M. F., Davidson, M. G. and Jones, M. D., 2011. Group 4 initiators for the stereoselective ROP of rac-β-butyrolactone and its copolymerization with rac-lactide. Chemical Communications, 47 (45), pp. 12328-12330.

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Official URL:

http://dx.doi.org/10.1039/c1cc15265c

Abstract

In this paper we demonstrate the utility of Group 4 metals for the well-controlled and stereoselective (syndiotactic) ring opening polymerization (ROP) of rac-beta-butyrolactone (BBL) and their ability to form copolymers.

Details

Item Type Articles
CreatorsJeffery, B. J., Whitelaw, E. L., Garcia-Vivo, D., Stewart, J. A., Mahon, M. F., Davidson, M. G. and Jones, M. D.
DOI10.1039/c1cc15265c
DepartmentsFaculty of Science > Chemistry
RefereedYes
StatusPublished
ID Code27771

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