Ireland-Claisen rearrangement of substrates bearing chiral enol ether units
Reference:
Tellam, J. P. and Carbery, D. R., 2011. Ireland-Claisen rearrangement of substrates bearing chiral enol ether units. Tetrahedron Letters, 52 (45), pp. 6027-6029.
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Official URL:
http://dx.doi.org/10.1016/j.tetlet.2011.09.011
Abstract
The Ireland-Claisen [3,3]-sigmatropic rearrangement of an allylic glycinate bearing a remote chiral enol ether has been studied. Remote exopericyclic stereocontrol is achievable in this instance. The product from this rearrangement has been progressed through a formal total synthesis of the natural antibiotic, furanomycin.
Details
| Item Type | Articles |
| Creators | Tellam, J. P.and Carbery, D. R. |
| DOI | 10.1016/j.tetlet.2011.09.011 |
| Uncontrolled Keywords | sigmatropic, amino acid, furanomycin, rearrangement, ireland-claisen |
| Departments | Faculty of Science > Chemistry |
| Publisher Statement | Carbery_Tetrahedron-Letters_2011_52_45_6027.pdf: NOTICE: this is the author’s version of a work that was accepted for publication in Tetrahedron Letters. Changes resulting from the publishing process, such as peer review, editing, corrections, structural formatting, and other quality control mechanisms may not be reflected in this document. Changes may have been made to this work since it was submitted for publication. A definitive version was subsequently published in Tetrahedron Letters, vol 52, issue 45, 2011, DOI 10.1016/j.tetlet.2011.09.011; Carbery_Tetrahedron-Letters_2011_52_45_6027.doc: NOTICE: this is the author’s version of a work that was accepted for publication in Tetrahedron Letters. Changes resulting from the publishing process, such as peer review, editing, corrections, structural formatting, and other quality control mechanisms may not be reflected in this document. Changes may have been made to this work since it was submitted for publication. A definitive version was subsequently published in Tetrahedron Letters, vol 52, issue 45, 2011, DOI 10.1016/j.tetlet.2011.09.011 |
| Refereed | Yes |
| Status | Published |
| ID Code | 28013 |
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