Palladium-catalyzed isomerization of exo-methylenic allylic alcohols
Fordred, P. S., Niyadurupola, D. G., Wisedale, R. and Bull, S. D., 2009. Palladium-catalyzed isomerization of exo-methylenic allylic alcohols. Advanced Synthesis & Catalysis, 351 (14-15), pp. 2310-2314.
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Treatment of allylic alcohols containing a 1,1-disubstituted alkene with a palladium catalyst and hydrogen gas (1 bar) results in facile isomerization to their corresponding trisubstituted (E)-allylic alcohols, along with small amounts of the corresponding hydrogenated products.
|Creators||Fordred, P. S., Niyadurupola, D. G., Wisedale, R. and Bull, S. D.|
|Departments||Faculty of Science > Chemistry|
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