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Palladium-catalyzed isomerization of exo-methylenic allylic alcohols


Reference:

Fordred, P. S., Niyadurupola, D. G., Wisedale, R. and Bull, S. D., 2009. Palladium-catalyzed isomerization of exo-methylenic allylic alcohols. Advanced Synthesis & Catalysis, 351 (14-15), pp. 2310-2314.

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Official URL:

http://dx.doi.org/10.1002/adsc.200900309

Abstract

Treatment of allylic alcohols containing a 1,1-disubstituted alkene with a palladium catalyst and hydrogen gas (1 bar) results in facile isomerization to their corresponding trisubstituted (E)-allylic alcohols, along with small amounts of the corresponding hydrogenated products.

Details

Item Type Articles
CreatorsFordred, P. S., Niyadurupola, D. G., Wisedale, R. and Bull, S. D.
DOI10.1002/adsc.200900309
DepartmentsFaculty of Science > Chemistry
RefereedYes
StatusPublished
ID Code28529

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