Dicyclohexylammonium trimethylbis(hydrogen phenylphosphonato)stannate(IV)

Reference:

Diop, T., Diop, L., Diop, C. A. K., Molloy, K. C. and Kociok-Kohn, G., 2011. Dicyclohexylammonium trimethylbis(hydrogen phenylphosphonato)stannate(IV). Acta Crystallographica Section E-Structure Reports Online, 67 (12), M1872-U1147.

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Official URL:

http://dx.doi.org/10.1107/s1600536811049567

Related URLs:

• http://dx.doi.org/10.1107/s1600536811049567

Abstract

In the title compound, (C(12)H(24)N)[Sn(CH(3))(3)(C(6)H(6)O(3)P)(2)], the SnMe(3) residues are axially coordinated by two monodentate [PhPO(3)H](-) anions, leading to a trigonal-bipyramidal geometry for the Sn(IV) atom. The two [SnMe(3)(PhPO(3)H)(2)](-) anions in the unit cell are associated into infinite chains along the a axis by O-H center dot center dot center dot O hydrogen bonds involving the hydroxy group of the hydrogen phenylphosphonate ion. The chains interact with one another via O-H center dot center dot center dot O hydrogen bonds along the c axis. These networks of anions assemble with the dicyclohexylammonium ion through N-H center dot center dot center dot O hydrogen bonds, forming a three-dimensional network.

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