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O2 insertion into a cadmium-carbon bond: structural characterization of organocadmium peroxides


Reference:

Johnson, A. L., Hollingsworth, N., Kociok-Kohn, G. and Molloy, K. C., 2012. O2 insertion into a cadmium-carbon bond: structural characterization of organocadmium peroxides. Angewandte Chemie-International Edition, 51 (17), pp. 4108-4111.

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Official URL:

http://dx.doi.org/10.1002/anie.201200448

Abstract

Cadmium burning: The violent reaction of CdMe 2 with O 2 has been controlled by the use of a cadmium aminoalkoxide supporting ligand. The first examples of cadmium organoperoxides, arising from O 2 insertion into the Cd C bond, are thus formed (see picture; Cdgreen, Cgray, Nblue, Ored).

Details

Item Type Articles
CreatorsJohnson, A. L., Hollingsworth, N., Kociok-Kohn, G. and Molloy, K. C.
DOI10.1002/anie.201200448
DepartmentsFaculty of Science > Chemistry
RefereedYes
StatusPublished
ID Code29692

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