Calix[4]arene-based metal-organic frameworks: Towards hierarchically porous materials

Reference:

Bew, S. P., Burrows, A. D., Düren, T., Mahon, M. F., Moghadam, P. Z., Sebestyen, V. M. and Thurston, S., 2012. Calix[4]arene-based metal-organic frameworks: Towards hierarchically porous materials. Chemical Communications, 48 (40), pp. 4824-4826.

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Official URL:

http://dx.doi.org/10.1039/c2cc30988b

Abstract

An upper rim-functionalised calix[4]arene dicarboxylic acid (H 2caldc) has been used to prepare four metal-organic frameworks, three of which have been structurally characterised and shown to form two- or three-dimensional network structures. Simulations suggest that such networks are likely to display interesting selectivity to guest molecules.

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