Supramolecular organotin tris-carboxylates: Crystal and molecular structure of [Cy 2NH 2] 2[1-Me 3(H 2O)SnOCO-3,5-(OOC) 2C 6H 3]·EtOH
Ndoye, D., Diop, L., Molloy, K. C. and Kociok-Kohn, G., 2012. Supramolecular organotin tris-carboxylates: Crystal and molecular structure of [Cy 2NH 2] 2[1-Me 3(H 2O)SnOCO-3,5-(OOC) 2C 6H 3]·EtOH. Main Group Metal Chemistry, 35 (1-2), pp. 59-61.
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The crystal and molecular structure of [Cy 2NH 2] 2[C 6H 3(CO 2) 3SnMe 3•H 2O]•CH 3CH 2OH (1) has been determined by single crystal X-ray diffraction analysis. In this compound, the tin atom is pentacoordinated by three methyl groups, one oxygen atom of a water molecule and one oxygen atom deriving from the tris-carboxylato ligand, in a trans-coordinated O 2SnC 3 environment. The dicyclohexylammonium cations are involved in intermolecular hydrogen bonds with the non-coordinated oxygen atoms of the carboxylate, while, along with hydrogen bonds involving water and ethanol, gives rise to a complex 3D lattice structure.
|Creators||Ndoye, D., Diop, L., Molloy, K. C. and Kociok-Kohn, G.|
|Departments||Faculty of Science > Chemistry|
|Publisher Statement||Molloy_Main-Group-Met-Chem_2012_35_1-2_59.pdf: The final publication is available at www.degruyter.com|
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