Supramolecular organotin tris-carboxylates: Crystal and molecular structure of [Cy 2NH 2] 2[1-Me 3(H 2O)SnOCO-3,5-(OOC) 2C 6H 3]·EtOH

Reference:

Ndoye, D., Diop, L., Molloy, K. C. and Kociok-Kohn, G., 2012. Supramolecular organotin tris-carboxylates: Crystal and molecular structure of [Cy 2NH 2] 2[1-Me 3(H 2O)SnOCO-3,5-(OOC) 2C 6H 3]·EtOH. Main Group Metal Chemistry, 35 (1-2), pp. 59-61.

Related documents:

PDF (Molloy_Main-Group-Met-Chem_2012_35_1-2_59.pdf) - Repository staff only until 01 June 2013 - Requires a PDF viewer such as GSview, Xpdf or Adobe Acrobat Reader Download (305kB) | Contact Author

Official URL:

http://dx.doi.org/10.1515/mgmc-2012-0907

Abstract

The crystal and molecular structure of [Cy 2NH 2] 2[C 6H 3(CO 2) 3SnMe 3•H 2O]•CH 3CH 2OH (1) has been determined by single crystal X-ray diffraction analysis. In this compound, the tin atom is pentacoordinated by three methyl groups, one oxygen atom of a water molecule and one oxygen atom deriving from the tris-carboxylato ligand, in a trans-coordinated O 2SnC 3 environment. The dicyclohexylammonium cations are involved in intermolecular hydrogen bonds with the non-coordinated oxygen atoms of the carboxylate, while, along with hydrogen bonds involving water and ethanol, gives rise to a complex 3D lattice structure.

Export

Actions (login required)