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Conversion of primary amines into secondary amines on a metal–organic framework using a tandem post-synthetic modification


Reference:

Burrows, A. D. and Keenan, L. L., 2012. Conversion of primary amines into secondary amines on a metal–organic framework using a tandem post-synthetic modification. CrystEngComm, 14 (12), pp. 4112-4114.

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    Official URL:

    http://dx.doi.org/10.1039/c2ce25131k

    Abstract

    The amine-functionalised metal-organic framework (MOF) [Zn 4O(bdc-NH 2) 3] (IRMOF-3, bdc-NH 2 = 2-amino-1,4-benzenedicarboxylate) has been post-synthetically modified in a tandem condensation-reduction process into secondary amine-containing MOFs. The degree of modification is enhanced by introduction of methanol, which helps to remove boron-containing side-products from the pores.

    Details

    Item Type Articles
    CreatorsBurrows, A. D.and Keenan, L. L.
    DOI10.1039/c2ce25131k
    DepartmentsFaculty of Science > Chemistry
    RefereedYes
    StatusPublished
    ID Code30649

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