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Dimethylammonium dichloridotriphenylstannate(IV)


Reference:

Sow, Y., Diop, L., Kociok-Kohn, G. and Molloy, K.C., 2012. Dimethylammonium dichloridotriphenylstannate(IV). Acta Crystallographica Section E-Structure Reports Online, 68 (7), m1015-m1016.

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Official URL:

http://dx.doi.org/10.1107/S1600536812028905

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Abstract

The title salt, [(CH 3) 2NH 2][Sn(C 6H 5) 3Cl 2], was obtained as a by-product of the reaction between bis(dimethylammonium) oxalate and triphenyltin chloride. In the stannate anion, the trigonal-bipyramidal coordination environment of the Sn IV atom is defined by the phenyl groups in equatorial and the Cl atoms in axial positions. The cations are connected to adjacent anions through N - H⋯Cl and C - H⋯Cl hydrogen-bonding interactions, leading to a chain motif parallel to [100].

Details

Item Type Articles
CreatorsSow, Y., Diop, L., Kociok-Kohn, G. and Molloy, K.C.
DOI10.1107/S1600536812028905
Related URLs
URLURL Type
http://dx.doi.org/10.1107/S1600536812028905Free Full-text
DepartmentsFaculty of Science > Chemistry
RefereedYes
StatusPublished
ID Code31036

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