Biomimetic flavin-catalyzed aldehyde oxidation
Reference:
Murray, A. T., Matton, P., Fairhurst, N. W. G., John, M. P. and Carbery, D. R., 2012. Biomimetic flavin-catalyzed aldehyde oxidation. Organic Letters, 14 (14), pp. 3656-3659.
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Official URL:
http://dx.doi.org/10.1021/ol301496m
Abstract
The oxidation of alkyl and aryl aldehydes to their corresponding carboxylic acids has been achieved through the action of a biomimetic bridged flavin catalyst. The reaction uses readily available 35% aqueous hydrogen peroxide and is operationally simple. The oxidation is a green and sustainable reaction, obviating chlorinated solvents with minimal byproducts.
Details
| Item Type | Articles |
| Creators | Murray, A. T., Matton, P., Fairhurst, N. W. G., John, M. P. and Carbery, D. R. |
| DOI | 10.1021/ol301496m |
| Departments | Faculty of Science > Chemistry |
| Publisher Statement | Carbery_Org_Lett_2012_14_14_3656.pdf: This document is the Accepted Manuscript version of a Published Work that appeared in final form in Organic Letters, copyright © American Chemical Society after peer review and technical editing by the publisher. To access the final edited and published work see http://dx.doi.org/10.1021/ol301496m |
| Refereed | Yes |
| Status | Published |
| ID Code | 31072 |
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