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Biomimetic flavin-catalyzed aldehyde oxidation


Reference:

Murray, A. T., Matton, P., Fairhurst, N. W. G., John, M. P. and Carbery, D. R., 2012. Biomimetic flavin-catalyzed aldehyde oxidation. Organic Letters, 14 (14), pp. 3656-3659.

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    Official URL:

    http://dx.doi.org/10.1021/ol301496m

    Abstract

    The oxidation of alkyl and aryl aldehydes to their corresponding carboxylic acids has been achieved through the action of a biomimetic bridged flavin catalyst. The reaction uses readily available 35% aqueous hydrogen peroxide and is operationally simple. The oxidation is a green and sustainable reaction, obviating chlorinated solvents with minimal byproducts.

    Details

    Item Type Articles
    CreatorsMurray, A. T., Matton, P., Fairhurst, N. W. G., John, M. P. and Carbery, D. R.
    DOI10.1021/ol301496m
    DepartmentsFaculty of Science > Chemistry
    Publisher StatementCarbery_Org_Lett_2012_14_14_3656.pdf: This document is the Accepted Manuscript version of a Published Work that appeared in final form in Organic Letters, copyright © American Chemical Society after peer review and technical editing by the publisher. To access the final edited and published work see http://dx.doi.org/10.1021/ol301496m
    RefereedYes
    StatusPublished
    ID Code31072

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