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Toward preparative resolution of chiral alcohols by an organic chemical method


Reference:

Malic, N., Moorhof, C., Sage, V., Saylik, D., Teoh, C.-M., Scott, J. L. and Strauss, C. R., 2010. Toward preparative resolution of chiral alcohols by an organic chemical method. New Journal of Chemistry, 34 (3), pp. 398-402.

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http://dx.doi.org/10.1039/b9nj00768g

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Abstract

Asymmetric alcohols were resolved as 1-α-O-alkyl-2,3-unsaturated hexosides. After separation of diastereoisomers, the auxiliary and the enantiomeric alcohol were recovered by transglycosidation. Potential applications include resolution of labile secondary and tertiary alcohols, difficult by existing techniques, and enhancement of ees of chiral alcohols produced enzymatically or by synthetic catalytic methods.

Details

Item Type Articles
CreatorsMalic, N., Moorhof, C., Sage, V., Saylik, D., Teoh, C.-M., Scott, J. L. and Strauss, C. R.
DOI10.1039/b9nj00768g
Related URLs
URLURL Type
http://www.scopus.com/inward/record.url?scp=77949421516&partnerID=8YFLogxKUNSPECIFIED
DepartmentsFaculty of Science > Chemistry
Research CentresCentre for Sustainable Chemical Technologies
RefereedYes
StatusPublished
ID Code34378

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