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Bespoke synthesis of unsymmetrical diaminoboranes by alkaline earth catalysis


Reference:

Bellham, P., Hill, M.S., Kociok-Kohn, G. and Liptrot, D.J., 2013. Bespoke synthesis of unsymmetrical diaminoboranes by alkaline earth catalysis. Chemical Communications, 49 (19), pp. 1960-1962.

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http://dx.doi.org/10.1039/c3cc39072a

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Abstract

Heavier group 2 (Mg, Ca) bis(trimethylsilyl)amides are catalysts for the formation of unsymmetrical diaminoboranes, [(R2N) BH(NR′2)], by dehydrocoupling of amine boranes and protic amines; a process which is proposed to occur by a sequential metal-centred elimination-insertion-elimination mechanism.

Details

Item Type Articles
CreatorsBellham, P., Hill, M.S., Kociok-Kohn, G. and Liptrot, D.J.
DOI10.1039/c3cc39072a
Related URLs
URLURL Type
http://www.scopus.com/inward/record.url?scp=84873637764&partnerID=8YFLogxKUNSPECIFIED
DepartmentsFaculty of Science > Chemistry
Research CentresCentre for Sustainable Chemical Technologies
RefereedYes
StatusPublished
ID Code35067

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