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The first crystallographically-characterised Cu(II) xanthate


Reference:

Johnson, A.L., Hill, M.S., Kociok-Kohn, G., Molloy, K.C. and Sudlow, A.L., 2014. The first crystallographically-characterised Cu(II) xanthate. Inorganic Chemistry Communications, 49, pp. 8-11.

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    Official URL:

    http://dx.doi.org/10.1016/j.inoche.2014.09.003

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    Abstract

    The copper(II) xanthate Cu(S2COEt)2·TMEDA (1)(TMEDA = N,N-tetramethylethylenediamine) has been synthesised and is the first structurally-characterised xanthate of copper in the + 2 oxidation state. 1 has an octahedral cis, cis, cis-ligand arrangement about the metal, in which xanthate chelation is markedly asymmetric. Both bulk thermal decomposition and film growth by aerosol-assisted chemical vapour deposition (AACVD) using 1 as precursor lead to the formation of Cu2S.

    Details

    Item Type Articles
    CreatorsJohnson, A.L., Hill, M.S., Kociok-Kohn, G., Molloy, K.C. and Sudlow, A.L.
    DOI10.1016/j.inoche.2014.09.003
    Related URLs
    URLURL Type
    http://www.scopus.com/inward/record.url?scp=84907463887&partnerID=8YFLogxKUNSPECIFIED
    DepartmentsFaculty of Science > Chemistry
    Research CentresCentre for Sustainable Chemical Technologies
    RefereedYes
    StatusPublished
    ID Code41791

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