Towards sustainable materials for solar energy conversion: Preparation and photoelectrochemical characterization of Cu2ZnSnS4
Scragg, J. J., Dale, P. J. and Peter, L. M., 2008. Towards sustainable materials for solar energy conversion: Preparation and photoelectrochemical characterization of Cu2ZnSnS4. Electrochemistry Communications, 10 (4), pp. 639-642.
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The feasibility of a new fabrication route for films of the attractive solar absorber Cu2ZnSnS4 (CZTS) has been studied, consisting of electrodeposition of metallic precursors followed by annealing in sulfur vapour. Photoelectrochemical measurements using a Eu3+ contact have been used to establish that the polycrystalline CZTS films are p-type with doping densities in the range (0.5-5) x 10(16) cm(-3) and band gaps of 1.49 +/- 0.01 eV, making them suitable for terrestrial solar energy conversion. It has been shown that a somewhat Cu-poor composition favours good optoelectronic properties. (C) 2008 Elsevier B.V. All rights reserved.
|Creators||Scragg, J. J., Dale, P. J. and Peter, L. M.|
|Departments||Faculty of Science > Chemistry|
|Additional Information||ID number: ISI:000255818500032|
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